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The nature of the phosphorus-metal bond in triphenylphosphine—transition metal complexes (Pd[P(C6H5)3]4, Rh(CO)Cl[P(C6H5)3]2 and Ir(CO)Cl[P(C6H5)3]2. A direct determination of the importance of P3d and PC σ∗ orbitals in ‘back-bonding’ by X-ray emission spectroscopy

Author:

Caroline Bourg,Stuart Gamblin,David S Urch

Publication:

Journal of Electron Spectroscopy and Related Phenomena

Publisher:

Elsevier

Date:

3 July 1995

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